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Metal-air batteries (MABs) have attracted attention because of their high specific energy, low cost, and safety features. This book discusses science and technology including material selection, synthesis, characterization, and their applications in MABs. It comprehensively describes various composite bifunctional electrocatalysts, corrosion/oxidation of carbon-containing air cathode catalysts, and how improvements can be achieved in the catalytic activities of oxygen reduction reaction and oxygen evolution reaction and their durability/stability. This book also analyzes, compares, and discusses composite bifunctional electrocatalysts in the applications of MABs, matching the fast information of commercial MABs in requirements. Aimed at researchers and industry professionals, this comprehensive work provides readers with an appreciation for what bifunctional composite electrocatalysts are capable of, how this field has grown in the past decades, and how bifunctional composite electrocatalysts can significantly improve the performance of MABs. It also offers suggestions for future research directions to overcome technical challenges and further facilitate research and development in this important area.