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This book comprehensively addresses advanced nanofiber manufacturing based on electrospinning technology. The principles, relationships between process parameters and structure, morphology and performance of electrospun nanofibers and nanomaterials, and the methods for enhanced field intensity and uniform distribution are discussed. The electric field intensity and distribution during electrospinning is also analyzed based on finite element analysis on both the needle and the needleless electrospinning. Furthermore, the modification techniques for improved nanomaterials strength are covered, aiming to provide effective avenues towards the manufacture of stronger nanofiber or nanomaterial products.