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Nature employs various switching mechanisms. The weather changes, the swiftness from day to night are some examples. According to the changes created by Mother Nature, all living entities adapt to the changes. In the era of scientific advancement, numerous techniques mushroom and get implemented. A lot of advancement has been with molecular switches. This book mainly focuses on organic and Nanomaterial based switches. Molecular switches and their activities in Plants and biological cycles are discussed. Also, the molecular switches in the sensory application are described in detail. The recently reported research on the themes mentioned above is briefly explained and quoted in the various chapters. This book mainly focuses on Organic and Nanomaterial based switches. Molecular switches and their activities in Plants and biological cycles are also discussed in detail. Molecular switches in the sensory application are explored. The recently reported research on the themes mentioned above is briefly explained and quoted in this book's upcoming chapters.