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Thermodynamics is a self-contained analysis of physical and chemical processes, based on classical thermodynamic principles. Emphasis is placed on the fundamental principles, with a conbination of theory and practice, and demonstrating their application to a variety of disciplines. Included in this work are new approaches to irreversible processes, electromagnetic effects, adsorption phenomena, self-assembly, the origin of phase diagrams, critical phenomena, and Caratheodory's treatment of the second law. This book will appeal to graduate students and professional chemists and physicists who wish to acquire a more sophisticated overview of thermodynamics and related subject matter.