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Understanding the rheological properties of fresh concrete, the hydration phenomenon of cement responsible for structuration, the relationship between the characteristics of the porous solid obtained and its mechanical performances or resistance to the aggressive penetration requires a complex knowledge of the physicochemistry of reactive porous materials. The development of simple formulation rules therefore requires the assimilation of this knowledge and a good command of the properties of these materials. The purpose of this book is to provide the mix designer with useful knowledge on granular materials and porous materials, which will enable the innovative design of concrete. Topics covered include the characterization of granular materials, the concepts of porosity and specific surface area, and the transport properties (diffusion and permeation) of concrete. Some of these topics are already covered in other general books dedicated to granular or porous materials. The objective here is to bring them together in one book by adapting them for use by concrete specialists. Applications in the form of exercises are offered at the end of each chapter to enable readers to assimilate the theoretical knowledge and to apply such knowledge to concrete problems encountered in civil engineering. Contents 1. Description of Granular Materials, Definitions. 2. Granulometry. 3. Specific Surface Area of Materials. 4. Voids in Granular Materials and the Arrangement of Grains. 5. Voids in Concrete. 6. The Fundamentals of Diffusion. 7. Permeability.